Improving the efficiency of hydrogen storage in LaNi5-based materials through cobalt modification


Miniyazov A. Skakov M. Mukhamedova N. Skopchenko M. Oken O. Sabyrtayeva A. Sokolov I. Nassyrova A.
January 2025AIMS Press

AIMS Energy
2025#13Issue 61417 - 1431 pp.

This paper investigated the effect of cobalt on hydrogen storage in the intermetallic compound LaNi5. Phase composition and hydrogen absorption properties of the LaNi5–хCoх system were analyzed using X-ray diffraction. The results demonstrated the retention of the hexagonal AB5-type structure upon substitution of nickel atoms with cobalt atoms, accompanied by minor changes in lattice parameters and the formation of the LaNi5Co phase. Hydrogen absorption studies revealed an increase in the material’s capacity to 1.9% and a reduction in the time required to reach 90% of the equilibrium concentration to 2–3 minutes. These findings indicate that cobalt modification is an effective method to enhance hydrogen storage efficiency.

cobalt , hydrogen storage , LaNi5 , metal hydride , spark plasma sintering

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National Nuclear Centre RK, Kurchatov, 071100, Kazakhstan
Department of Technical Physics and Heat Power Engineering, Shakarim University, Semey, 071410, Kazakhstan
S.Amanzholov East Kazakhstan University, Kamenogorsk, 070004, Kazakhstan

National Nuclear Centre RK
Department of Technical Physics and Heat Power Engineering
S.Amanzholov East Kazakhstan University

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