Structural and electronic transition of layered PtSe2 into non-layered PtSe


Zhussupbekov K. Berman S. Prechtl M. Busch M. Zhussupbekova A. Duesberg G.S. Nicolosi V. Novoselov K.S. Ó Coileáin C. Shvets I.V.
28 January 2025Royal Society of Chemistry

Nanoscale
2025#17Issue 95249 - 5258 pp.

Research into novel two-dimensional (2D) materials has boomed over the past decade, with a bewildering diversity of distinct properties being discovered. In this work, layered PtSe2, grown by chemical vapor deposition and thermally converted to non-layered tetragonal PtSe, is experimentally and theoretically investigated. Notably, the resultant PtSe is distinctly metallic, which highlights the significance of sub-stoichiometric phases within transition metal dichalcogenide films. This shows that thermal conversion can drastically affect the atomic and electronic properties of these phases.



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School of Physics, Trinity College Dublin, Dublin 2, Ireland
School of Chemistry, Trinity College Dublin, Dublin 2, Ireland
Kh. Dosmukhamedov Atyrau University, Studenchesky Ave., 1, Atyrau, Kazakhstan
Institute of Physics, EIT 2, Faculty of Electrical Engineering and Information Technology, SENS Research Center, University of the Bundeswehr Munich, Germany
Institute for Functional Intelligent Materials, National University of Singapore, 4 Science Drive 2, 117544, Singapore
National Graphene Institute, University of Manchester, Oxford Road, Manchester, M13 9PL, United Kingdom

School of Physics
School of Chemistry
Kh. Dosmukhamedov Atyrau University
Institute of Physics
Institute for Functional Intelligent Materials
National Graphene Institute

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