Synergistic purification of chromium-containing wastewater via adsorption-photocatalysis induced by multiple defect-containing CuS/Cv-CNNs

Wang L. Ren Y. Zhao H. Li H. Niu X. Zhang D. Fan H. Wang K.
20 February 2024 Royal Society of Chemistry

New Journal of Chemistry
2024 #48 Issue 10 4507 - 4520 pp.

To address the water pollution problem caused by hexavalent chromium, this study took advantage of a multi-defect adsorption mechanism and constructed a multiple defect-containing type-II heterojunction material, CuS/Cv-CNNs. This material has simultaneous sulfur vacancies, copper vacancies, and carbon vacancies, which were used to accelerate the removal of chromium from wastewater. Attributed to the formation of electron-rich structures and free-moving ions by the construction of multiple defect sites, the photogenerated carriers generated by CuS/Cv-CNNs-70 were efficiently separated, and a high amount of physical Cr(vi) adsorption was achieved by electrostatic attraction and ion exchange, consistent with a Freundlich isothermal adsorption model. Studies on the adsorption thermodynamics demonstrate that CuS/Cv-CNNs-70 prefers to adsorb Cr(vi) when temperatures are raised. In addition, the removal of Cr(vi) (120 mg L⁻¹) by CuS/Cv-CNNs-70 reached 97.10% after 60 minutes through the synergistic effect of adsorption and visible-light photocatalysis. This finding indicates that the synergistic effect between the multilocation defects stimulated the combined potential of adsorption and photocatalysis of CuS/Cv-CNNs-70 to realize the full utilization of the defects. In conclusion, this study confirms the prominent role of a multiple defect mechanism in wastewater treatment and environmental protection.

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School of Petrochemical Technology, Lanzhou University of Technology, Lanzhou, 730050, China
Chemistry Department, Nazarbayev University, Astana, 010000, Kazakhstan

School of Petrochemical Technology
Chemistry Department

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