Glassy Metal–Organic Framework-Based Solid-State Electrolytes: Advance, Challenge, and Emerging Opportunities
Wang Y. Jiang G. Li J. Yang A. An B. Malchik F. Galeyeva A. Xu F. Wang H.
1 November 2025John Wiley and Sons Inc
Small Methods
2025#9Issue 11
Glassy metal–organic frameworks (MOFs) are amorphous porous materials constructed by inorganic metal ions and organic ligands. Owing to the unique features of abundant unsaturated metal sites, grain-boundary-free and isotropic attributes, glassy MOFs are emerging as a type of promising material platform in energy storage, especially as solid-state electrolytes. In this review, the mechanisms that promote ionic migration/conductivity and suppress the formation of lithium dendrites for glassy MOF-based electrolytes are briefly summarized. Different types of glassy MOF-based electrolytes are systematically introduced. Moreover, the influences of multiple factors on the performance of glassy MOF-based electrolytes are discussed, including the structural characteristics, pore sizes, the addition of ionic liquids, compositing with polymers, and the electronic effect. Finally, new insights and prospects for future development of glassy MOF-based electrolytes are presented to inspire innovative approaches for the commercial applications of MOF glass-based lithium metal batteries.
glass , glassy metal–organic frameworks , lithium metal batteries , solid-state electrolyte
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State Key Laboratory of Solidification Processing, Center for Nano Energy Materials, School of Materials Science and Engineering, Northwestern Polytechnical University and Shaanxi Joint Laboratory of Graphene (NPU), Shaanxi Laboratory of Advanced Materials, Xian, 710072, China
School of Chemical Engineering, University of Science and Technology Liaoning, Liaoning, Anshan, 114051, China
Center of Physical-Chemical Methods of Research and Analysis, Al-Farabi Kazakh National University, Almaty, 050040, Kazakhstan
State Key Laboratory of Solidification Processing
School of Chemical Engineering
Center of Physical-Chemical Methods of Research and Analysis
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