Investigation of the Process of Agglomeration of Phosphorites Using Phosphate-Siliceous Shales and Oil Sludge
Tleuova S. Tileuberdi A. Pazylova D. Ulbekova M. Sagyndykova N. Lavrov B. Turishbekov Z.
2024Bentham Science Publishers
Open Chemical Engineering Journal
2024#18
Introduction: This article aims to discuss the physico-chemical features of the agglomeration process of phosphorus fines using phosphate-siliceous shales and oil sludge. Methods: The composition and structure of the starting materials and physico-chemical transformations under thermal influence are studied using IR spectrometry and differential thermal analysis methods. Results: The results of IR spectrometric analysis of the phosphate siliceous shales are characterized by intense peaks at 493.78, 547.78, and 678.94 cm-1, corresponding to Ca-O-P compounds. Moreover, the wave oscillations in the region of 837.11-995.27 cm-1 indicate the characteristics of Si-O valence bonds, and in the region of 1114.86-1431 cm-1 depict the characteristics of Si-O-Al compounds. The IR spectrum of oil sludge is characterized by the presence of wave oscillations in the region of 1411.89-2904.80 cm-1 corresponding to petroleum components. Conclusion: The differential thermal analysis of the investigated sample of phosphate-siliceous shale does not have intense endo- and exo-effects, and it is characterized by a significant predominance of hydrate compounds of aluminosilicate and carbonate components.
Agglomeration , Carbonates , Hydrosilicates , Mathematical modelling , Oil sludge , Phosphate-siliceous shales , Phosphorites
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Chemical Engineering and Biotechnology High School, South Kazakhstan University named after M.Auezov, Kazakhstan, Shymkent, 160000, Kazakhstan
Department of General Chemical Technology and Catalysis, St.Petersburg State Technological Institute, Saint Petersburg, 190000, Russian Federation
Chemical Engineering and Biotechnology High School
Department of General Chemical Technology and Catalysis
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