The Concentration Quenching of Photoluminescence and the Quantum Yield in (Y1–xPrx)2O2Se Solid Solutions


Tarasenko M.S. Ryadun A.A. Orazov Z.K. Pomelova T.A. Zalesskii V.B. Malyutina-Bronskaya V.V. Fedorov V.E. Wang H.-C. Naumov N.G.
August 2021Pleiades journals

Inorganic Materials
2021#57Issue 8830 - 834 pp.

Abstract—: (Y1–xPrx)2O2Se solid solutions with х = 0.004, 0.008, 0.010, 0.012, and 0.020 have been prepared from oxides by ampule synthesis. We have measured their excitation spectra at λem = 514 nm and their photoluminescence and quantum yield spectra at λex = 463 nm (T = 300 K). Comparing their emission intensities at wavelengths of 514 (3P03H4 transition) and 670 nm (3P03F2 transition), we have determined the optimal dopant concentration (x = 0.01), at which the quantum yield has a maximum, reaching 3%.

concentration quenching , oxyselenide , photoluminescence , praseodymium , yttrium

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Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090, Russian Federation
Novosibirsk State University, Novosibirsk, 630090, Russian Federation
Al-Farabi Kazakh National University, Almaty, 050040, Kazakhstan
Optics, Optoelectronics, and Laser Engineering State Research and Production Corporation, Minsk, 220072, Belarus
Department of Mechanical Engineering and Advanced Institute of Manufacturing with High Tech Innovations, National Chung Cheng University, Chia-Yi, Min-Hsiung, 621, Taiwan

Nikolaev Institute of Inorganic Chemistry
Novosibirsk State University
Al-Farabi Kazakh National University
Optics
Department of Mechanical Engineering and Advanced Institute of Manufacturing with High Tech Innovations

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