ESR-Study of the Proton Exchange with Aliphatic Amino Acids in Toluene
Толуол ортадағы кейбір алифаттық аминқышқылдарымен протон алмасу реакциясын ЭПР әдісімен зерттеу
ЭПР-исследование реакции протонного обмена с некоторыми алифатическими аминокислотами в толуольной среде
Stadnik I.L. Abilkanova F.Z. Kudryavtseva Y.V. Nikolskiy S.N. Masalimov A.S.
2022E.A.Buketov Karaganda State University Publish House
Bulletin of the Karaganda University Chemistry Series
2022#106Issue 269 - 76 pp.
This paper presents the results of an ESR spectroscopic study of the intermolecular proton exchange kinetics with some isomers of aminocaproic acid, such as 2-aminohexanoic and 6-aminohexanoic acids in the toluene indifferent medium. A stable semiquinone radical, namely 3,6-di-tert-butyl-2-hydroxyphenoxyl, is used as a spin probe. The ESR spectra have been recorded on a RE-1306 spectrometer. The article provides the obtained dynamic spectra of the intermolecular proton exchange process. Modeling of the proton exchange ESR spectra has been carried out using a previously developed program, which is based on a four-jump model of this reaction and modified Bloch equations. The kinetic parameters of the process of acid-base interaction of the spin probe with amino acids and the activation barrier of the reaction have been estimated with a minimum error based on a comparison of the model spectra with the experimental ones. The obtained data have been analyzed and compared with previous studies. It has been found that the reaction rate of the intermolecular proton exchange between 3,6-di-tert-butyl-2-hydroxyphenoxy and studied aliphatic amino acids is comparable to the same with aliphatic carboxylic acids. Hoewever, in our case, there is an increase in the activation barrier, which apparently is associated with a negative effect on the intramolecular hydrogen bonding process between the amino and the carboxyl groups in the amino acid molecule.
3 , 6-di-tert-butyl-2-hydroxyphenoxyl , aminohexanoic acid , Bloch equation , ESR-spectroscopy , OH-acids , proton exchange reactions , semiquinone radical , spin probe
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Physical and Analytical Chemistry Department, Karagandy University of the name of academician E.A. Buketov, Universitetskaya street, 28, Karaganda, 100024, Kazakhstan
Physical and Inorganic Chemistry Department, Altay State University, Barnaul, 656049, Russian Federation
Physical and Analytical Chemistry Department
Physical and Inorganic Chemistry Department
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