Recycling of Low-Density Polyethylene Waste for Synthesis of Carbon Nanotubes
Smagulova G.T. Vassilyeva N. Kaidar B.B. Yesbolov N. Prikhod’ko N.G. Supiyeva Z. Artykbaeva M.T. Mansurov Z.A.
March 2021Springer
Journal of Engineering Physics and Thermophysics
2021#94Issue 2431 - 436 pp.
The authors have presented results of synthesis of carbon nanotubes from low-density polyethylene. The synthesis was carried by thermal destruction of the polyethylene in a chemical-vapor-deposition unit. The process of decomposition of the polyethylene and the synthesis of carbon nanotubes were implemented in one stage in a triple-fired furnace for chemical vapor deposition. Consideration has been given to the influence of temperature on the decomposition products of polyethylene in the range of temperatures 450–550oC. The gas- and vaporphase decomposition products of polyethylene, obtained at different temperatures, were investigated by the infrared spectroscopy method. It has been established that the necessary and suffi cient temperature of decomposition of polyethylene is 450oC. Carbon nanotubes were grown on a catalyst that represented cenospheres impregnated with a ferrous nitrate solution. On exposure to high temperatures, ferrous nitrate decomposes to form pure iron particles on the cenospheric surface, which are active sites of growth of carbon nanotubes. The formation of iron particles on the cenospheric surface upon the impregnation with ferrous nitrate and thermal treatment is confirmed by the results of x-ray phase analysis. A semiquantitative analysis shows that the content of iron in the total catalysts mass amounts to about 2.3%. The synthesis gives rise to carbon nanotubes with diameters of 50–60 nm on the cenospheric surface. Thus, it has been shown that carbon nanotubes can be synthesized from low-density polyethylene waste.
carbon nanotubes , cenospheres , decomposition , infrared spectroscopy , iron , low-density polyethylene
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Institute for Combustion Problems, 172 Bogenbai Batyr Str, Almaty, 050012, Kazakhstan
Al-Farabi Kazakh National University, 71 Al-Farabi Ave, Almaty, 050040, Kazakhstan
Almaty University of Power Engineering and Telecommunications, 126 Baytursynov Str, Almaty, 050013, Kazakhstan
Institute for Combustion Problems
Al-Farabi Kazakh National University
Almaty University of Power Engineering and Telecommunications
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