Approach for the Description of Chemical Equilibrium Shifts in the Systems with Free and Connected Chemical Reactions
Shaymardanov Z. Shaymardanova B. Kulenova N.A. Sadenova M.A. Shushkevich L.V. Charykov N.A. Semenov K.N. Keskinov V.A. Blokhin A.A. Letenko D.G. Kuznetsov V.V. Sadowski V.
December 2022MDPI
Processes
2022#10Issue 12
Approach for the description of chemical equilibrium shifts in the systems with free and connected chemical reactions was elaborated. Driving forces of chemical equilibrium shifts were temperature change (at P = const), pressure change (at T = const), and input or output of reagents or products (at T, P = const). It was demonstrated how the conditions for passing through the extremes of the state parameters (T, P, and components molar numbers) in one of the reactions transmitted to other reactions, connected with the first one by reagents or products.
chemical equilibrium shift , dependence of chemical variables on state parameters , extreme composition transfer between connected reactions , isolated and concurrent connected chemical reactions
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Department of Metallurgy, Center “Veritas”, East Kazakhstan State Technical University, A.K. Protozanov Street, 69, Ust-Kamenogorsk, 070004, Kazakhstan
Department of Physical Chemistry, Electrotechnical University «LETI», Professora Popova Str. 5, St. Petersburg, 197376, Russian Federation
Department of Physical Chemistry, Saint Petersburg State Technological Institute, Technical University, Moskovskii Pr., 26, St. Petersburg, 190013, Russian Federation
Department of General and Bioorganic Chemistry, Pavlov First Saint Petersburg State Medical University, L’va Tolstogo Str. 6–8, St. Petersburg, 197022, Russian Federation
Department of Solid-State Chemistry, Institute of Chemistry, Saint Petersburg State University, Universitetskii Pr. 26, St. Petersburg, 198504, Russian Federation
Faculty of Civil Engineering, Saint Petersburg State Architecture and Construction University, 2 Krasnoarmeyskaya Str. 4, St. Petersburg, 190005, Russian Federation
Faculty of Electronics, Telecommunications and Informatics, Digital Technologies Center, Gdansk University of Technology, ul. Gabriela Narutowicza 11/12, Gdańsk, 80-233, Poland
Department of Metallurgy
Department of Physical Chemistry
Department of Physical Chemistry
Department of General and Bioorganic Chemistry
Department of Solid-State Chemistry
Faculty of Civil Engineering
Faculty of Electronics
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