Catalytic cracking of M-100 fuel oil: relationships between origin process parameters and conversion products
Shakiyeva T.V. Sassykova L.R. Khamlenko A.A. Dzhatkambayeva U.N. Sassykova A.R. Batyrbayeva A.A. Zhaxibayeva Z.M. Ismailova A.G. Sendilvelan S.
2022Ural Federal University
Chimica Techno Acta
2022#9Issue 3
The development of technologies for processing oil residues is relevant and promising for Kazakhstan, since the main oil reserves of hydrocarbons in the country are in heavy oils. This paper describes the study of the influence of technological modes on the yield and hydrocarbon composition of products formed because of cracking of commercial fuel oil and fuel oil M-100 in the presence of air in the reactor. For catalysts preparation, natural Taizhuzgen zeolite and Narynkol clay were used. It was found that the introduction of air into the reaction zone, in which oxygen is the initiator of the cracking process, significantly increases the yield of the middle distillate fractions. In the presence of air, the yield of diene and cyclodiene hydrocarbons significantly increases compared to cracking in an inert atmosphere. According to the data of IR spectral analysis of M-100 grade oil fractions, in addition to normal alkanes, the final sample contains a significant amount of olefinic and aromatic hydrocarbons. On the optimal catalyst, owing to oxidative cracking of fuel oil, the following product compositions (in %) were established: Fuel oil M- 100: gas - 0.8, gasoline - 1.1, light gas oil - 85.7, heavy residue - 11.9, loss - 0.5 and total - 100.0%; commodity Fuel oil (M-100): gas - 3.3, gasoline - 8.4, light gas oil - 84.3, heavy residue - 4.0, loss - 0 and total - 100.0%.
Amangeldy GPP , catalytic cracking , fuel oil M-100 , Narynkol clay , natural zeolite , oxidative cracking , Taizhuzgen zeolite
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Al-Farabi Kazakh National University, Almaty, 050040, Kazakhstan
Almaty College of Economics and Law, Almaty, 050004, Kazakhstan
Abai Kazakh National Pedagogical University, Almaty, 050010, Kazakhstan
Department of Mechanical Engineering, Dr. M.G.R. Educational and Research Institute, Tamilnadu, 600095, India
Al-Farabi Kazakh National University
Almaty College of Economics and Law
Abai Kazakh National Pedagogical University
Department of Mechanical Engineering
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