Synthesis, Characterization, and Analysis of Bioplasticizers Derived from Thespesia populnea Leaf: Towards Sustainable Biomaterials


Senthamaraikannan P. Arokiasamy F.S. Selvan M.T. Divakaran D. Suyambulingam I. Balan A.V. Rao H.J.
July 2025Springer

Journal of Inorganic and Organometallic Polymers and Materials
2025#35Issue 75578 - 5595 pp.

This study presents a detailed synthesis, characterization, and analysis of bioplasticizers derived from Thespesia populnea leaf powder (TPLP) towards developing sustainable biomaterials. Comprehensive characterization of TPLP across various analytical techniques reveals its diverse properties and potential applications. Fourier-transform infrared (FTIR) spectroscopy indicates the cellulose, hemicellulose, pectin, lipids, lignin, and aromatic compounds. UV-visible absorption spectra suggest reduced transparency attributed particle interactions and crystalline structure. XRD analysis of TPLP shows the crystallinity value of 50.69% with crystalline size around 20.49 nm, indicative of its plasticizing effect. Particle size distribution analysis indicates an average size of 12.459 μm, while differential scanning calorimetry (DSC) analysis reveals multiple thermal transitions indicative of crystallization, melting, and decomposition. These findings collectively underscore TPLP’s versatility and potential across a range of applications, including use as a plasticizer in polymer films for packaging, drug delivery systems, composite materials, high-temperature applications such as phase change material formulations. This research highlights the promising future of TPLP as a sustainable bioplasticizer in various industrial applications.

Bioplasticizers , Characterization , Surface morphology , Sustainable biomaterials , Thermal analysis , Thespesia populnea

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Sophisticated Testing and Instrumentation Centre (STIC), Department of Mechanical Engineering, Alliance School of Applied Engineering, Alliance University, Karnataka, Bengaluru, 562106, India
Department of Mechanical Engineering, KIT-Kalaignarkarunanidhi Institute of Technology, Tamil Nadu, Coimbatore, 641402, India
Department of Mechanical Engineering, Dhanalakshmi Srinivasan College of Engineering, Tamil Nadu, Coimbatore, 641105, India
Department of Biotechnology, Saveetha School of Engineering, SIMATS, Tamil Nadu, Chennai, 602105, India
Department of Mechanical Engineering, K.S.R College of Engineering, KSR Kalvi Nagar, Tamil Nadu, Tiruchengode, India
Department of Mathematics, School of Sciences and Humanities, Nazarbayev University, Kabanbay Batyr 53, Astana, 010000, Kazakhstan

Sophisticated Testing and Instrumentation Centre (STIC)
Department of Mechanical Engineering
Department of Mechanical Engineering
Department of Biotechnology
Department of Mechanical Engineering
Department of Mathematics

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