The Influence of Annealing on the Structural, Optical and Electrical Properties of Copper Selenite Nanocrystals Synthesized by the Chemical Deposition Method
Sarsekhan G. Usseinov A. Akylbekova A. Akilbekov A. Dauletbekova A. Junisbekova D. Abdrakhmetova A. Aralbayeva G. Kassenova L. Baimukhanov Z.
December 2025Multidisciplinary Digital Publishing Institute (MDPI)
Crystals
2025#15Issue 12
This work presents a study of copper selenite nanocrystals, obtained for the first time by chemical deposition (template synthesis) in a SiO2/Si track template, and investigates their properties. The obtained nanostructures were subjected to structural, optical, and electrical analysis. After deposition, X-ray diffraction (XRD) analysis confirmed the formation of the orthorhombic phase CuSeO3. Subsequent annealing in a vacuum at 800 °C and 1000 °C led to successive phase transformations: to the monoclinic phase and, finally, to the triclinic polymorph of copper selenite. Photoluminescence (PL) analysis showed that the intensity and spectral position of the emission peaks vary depending on the crystal structure, which is associated with changes in defects and bandgap width as a result of heat treatment. Current–voltage characteristic (CVC) measurements showed that the phase composition significantly affects electrical conductivity. In particular, the transition to the triclinic phase after annealing at 1000 °C led to noticeable changes in optical and electrical properties compared to the initial material. Thus, a direct relationship has been established between heat treatment conditions, crystal structure, and functional properties of CuSeO3-based materials, opening up possibilities for their application in photonics and electronics.
chemical deposition , copper selenite , nanocrystals , photoluminescence , SiO2/Si track template
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Department of Thermal Power Engineering, L.N. Gumilyov Eurasian National University, Satpayev Str. 2, Astana, 010008, Kazakhstan
Department of Technical Physics, L.N. Gumilyov Eurasian National University, Satpayev Str. 2, Astana, 010008, Kazakhstan
Department of Thermal Power Engineering
Department of Technical Physics
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