ON THE TECHNOLOGY OF SYNTHESIS OF HYDROGENATED DIAMOND-LIKE THIN FILMS BY ION-PLASMA METHOD
ГИДРОГЕНИЗАЦИЯЛАНҒАН АЛМАЗТЕКТЕС ЖҰҚА ҚАБЫҚШАЛАРДЫ ИОНДЫ-ПЛАЗМАЛЫҚ ӘДІСПЕН СИНТЕЗДЕУ ТЕХНОЛОГИЯСЫ
О ТЕХНОЛОГИИ СИНТЕЗА ГИДРОГЕНИЗИРОВАННЫХ АЛМАЗОПОДОБНЫХ ТОНКИХ ПЛЕНОК ИОННО-ПЛАЗМЕННЫМ МЕТОДОМ
Ryaguzov A.P. Assembayeva A.R. Guseinov N.R. Bekmurat F.
2025Kazakh-British Technical University
Herald of the Kazakh British Technical UNiversity
2025#22Issue 2322 - 332 pp.
This work presents the synthesis of hydrogenated amorphous diamond-like carbon (HDLC) films using a magnetron method in a gas mixture of CH4+Ar. The synthesis of the HDLC films was carried out over a wide temperature range from 80 °C to 240 °C. The local structure of the synthesized samples was studied using Raman spectroscopy. Additionally, the mechanical and optical properties of the obtained thin diamond-like carbon films were investigated. The dependence of the studied characteristics on the synthesis conditions was demonstrated. It was found that the substrate temperature significantly influences the formation of the structure and properties of hydrogenated diamond-like carbon films. The dependence of the bandgap on the substrate temperature was shown. It was revealed that the bandgap of the synthesized hydrogenated samples decreases from 1.78 eV to 1.63 eV as the temperature increases from 80°C to 240°C. This can be attributed to the increase in sp² hybridized bonds and the growth of π-electron density states. It was also shown that the change in microhardness of hydrogenated diamond-like carbon films correlates with the change in optical bandgap. Microhardness, evaluated using the Knoop method, was found to range from 37.5×10² kgf/mm² to 29.5×10² kgf/mm², depending on the substrate temperature. This change in microhardness confirms the decrease in sp³ hybridized bonds in the film structure.
diamond-like carbon film , forbidden band width , hydrogenated , microhardness , Raman spectroscopy
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NNLOT Al-Farabi Kazakh National University, Almaty, Kazakhstan
Satbayev University, Almaty, Kazakhstan
NNLOT Al-Farabi Kazakh National University
Satbayev University
10 лет помогаем публиковать статьи Международный издатель
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