Synthesis and evaluation of corrosion inhibitory and adsorptive properties of N-(β-ethoxypropionitrile-N,N-bis(2-hydroxyethylethoxy) fatty amide
Rakhymbay G. Jumanova R. Avchukir K. Bakhytzhan Y. Argimbayeva A. Burkitbayeva B. Turmukhanova M. Vacandio F. Adeloye A.
29 September 2021Royal Society Publishing
Royal Society Open Science
2021#8Issue 9
The present study reports a synthetic condensation process of a vegetable oil (waste) reacted with triethanolamine, maleic anhydride and acrylonitrile in (1: 1.2: 2: 1) mole ratios to obtain N-(β-ethoxypropionitrile)-N,N-bis(2-hydroxyethylethoxy) fatty amide as a major inhibitory product. Corrosion property of steel in a 3% NaCl solution in the presence of a potential inhibitor was investigated using weight loss, potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) methods. These methods gave consistent results, from which it is noticeable that inhibition efficiency increases with the increasing concentration of the inhibitor. Gravimetric studies show an increase in the sample mass at an inhibitor concentration of 10 mM, indicative of adsorbed film formation on the surface. The polarization curve results showed that the compound demonstrates itself as an anodic-type inhibitor. A rise in polarization resistance values in the EIS measurements also confirmed that the compound acts as an effective inhibitor of steel corrosion. Furthermore, the R(CR)(QR) equivalent circuit was used to interpret the results obtained in the investigation of the corrosion behaviour of steel in solution with an inhibitor. The standard adsorption free energies calculated from the Langmuir isotherm indicate that adsorption takes place by physical and chemical mechanisms. The presence of adsorbed protective film was confirmed by FT-IR spectrum and SEM micrographs.
adsorption , corrosion , ester amide derivative , impedance , inhibition efficiency , steel
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Center of Physical Chemical Methods of Research and Analysis, Al-Farabi Kazakh National University, 71 al-Farabi Ave., Almaty, 050040, Kazakhstan
Aix-Marseille University, CNRS, MADIREL UMR 7246, Marseille Cedex 20, 13397, France
Center of Physical Chemical Methods of Research and Analysis
Aix-Marseille University
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