Ethers and Their Oligomeric Derivatives Obtained from 2,4,6,8-Tetra(hydroxymethyl)glycoluril
Panshina S.Y. Ponomarenko О.V. Bakibaev A.A. Malkov V.S. Zhortarova A.A.
December 2023Pleiades Publishing
Russian Journal of General Chemistry
2023#93S456 - S462 pp.
Abstract: In this work, a series of 2,4,6,8-tetra(alkoxymethyl)glycoluril esters and their derivatives was synthesized for the first time, starting from 2,4,6,8-tetra(hydroxymethyl)glycoluril, the properties and spectral data of the synthesized compounds were described. Individual oligomers, derivatives of 2,4,6,8-tetra(methoxymethyl)glycoluril, were isolated and identified, their structures were described using HPLC analysis and IR and NMR spectroscopy. A similar possibility for the dimerization/oligomerization reactions of 2,4,6,8-tetra(ethoxymethyl)-, 2,4,6,8-tetra(isopropoxymethyl)-, and 2,4,6,8-tetra(butoxymethyl) derivatives of glycoluril with the release of macrocomponents was shown.
1-hydroxyethylidenediphosphonic acid , 2,4,6,8-tetra(alkoxymethyl)glycolurils , 2,4,6,8-tetra(hydroxymethyl)glycoluril , 2,4,6,8-tetra(methoxymethyl)glycoluril , oligomers
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Karaganda Buketov University, Karaganda, 100028, Kazakhstan
Kokshetau Shoqan Ualikhanov University, Kokshetau, 020000, Kazakhstan
National Research Tomsk State University, Tomsk, 634050, Russian Federation
Karaganda Buketov University
Kokshetau Shoqan Ualikhanov University
National Research Tomsk State University
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