Production of electrolytic copper from Zhezkazgan Processing Plant tailings leaching solutions using a hydro-impulse discharge


Жезқазған байыту фабрикасы қалдықтарына гидроимпульсті разрядты қолдана отырып, ерітінділерінен электролиттік мысты алу
Получение электролитической меди из растворов выщелчивания хвостов Жезказганской обогатительной фабрики с применением гидроимпульсного разряда
Mustafin Y.S. Omarov K.B. Borsynbaev A.S. Havlichek D. Pudov A.M. Shuyev N.V.
2021E.A.Buketov Karaganda State University Publish House

Bulletin of the Karaganda University Chemistry Series
2021#104Issue 4128 - 137 pp.

In this work, for the first time, studies of the mineralogical composition and chemical semi-quantitative spec-tral analysis (SQSA) of the Zhezkazgan processing plant tailings before and after leaching were carried out. It was found that copper is present in the tailings in the form of the chalcosine and bornite minerals. After leaching with the use of ammonium bifluoride and a hydro-pulse discharge, chalcosine and boronite are de-stroyed, and copper passes into a solution containing phosphoric acid. As a result of multiple placing of tail-ings into the solution, the copper content in it is brought to a concentration at which copper deposition on a stainless steel plate is possible. The identification of copper was implemented on a LAES-Matrix grain spec-trometer. A visual comparative analysis of the changes in the structure of the treated ore waste was carried out using a TESCAN MIRA scanning electron microscope. Metallic copper was obtained from solution by electrochemical reactions in an experimental laboratory setup as a result. The technology was developed on an experimental laboratory setup for the extraction of metallic copper and brought the choice of the solution medium and electrochemical processes to the stage of obtaining the target metal with a purity of 99.99 %.

Ammonium hydrofluoride , Copper , Electrolysis , Hydro-impulse discharge , Mineralogical composition , Pulp , Reactor , Tailings samples

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Karagandy University of the Name of Academician E.A. Buketov, Karaganda, Kazakhstan
Charles University, Prague, Czech Republic

Karagandy University of the Name of Academician E.A. Buketov
Charles University

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