Enhanced adsorption of emerging contaminants from pharmaceutical wastewater using alkaline-treated pineapple leaf fiber integrated with UV-LED technology


Mkilima T. Saspugayeva G. Kaliyeva G. Samatova I. Rakhimova B. Tuleuova G. Tauyekel A. Batyayeva Y. Karibzhanova R. Cherkeshova S.
December 2024Elsevier Ltd

Case Studies in Chemical and Environmental Engineering
2024#10

The alarming rise of pharmaceutical contaminants in wastewater poses a significant environmental and public health challenge. Addressing this issue, this study investigated the potential of alkaline-treated pineapple leaf fiber (PALF) as an eco-friendly adsorbent for pharmaceutical removal, coupled with UV-LED technology. Alkaline treatment enhanced PALFs adsorption capabilities, increasing surface area to 68.3 m2/g and pore volume to 0.120 cm³/g. Adsorption experiments showed high efficiencies (up to 89.7 % for ciprofloxacin, 88.5 % for paracetamol, and 77.1 % for ibuprofen), following a pseudo-second-order kinetic model. Isotherm analysis indicated a maximum adsorption capacity of 35.4 mg/g for ciprofloxacin. PALF maintained 85.9 % removal efficiency after five regeneration cycles, with no adverse effects on aquatic organisms observed in toxicity assays. This research highlights PALFs promise as a sustainable solution for pharmaceutical wastewater treatment, aligning with the focus on environmental sustainability and innovative materials.

Adsorption , Hospital wastewater , Pharmaceutical contaminants , Pineapple leaf fiber , Sustainable adsorbent , Wastewater treatment

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Department of Environmental Engineering and Management, The University of Dodoma, 1 Benjamin Mkapa Road, Iyumbu, Dodoma, 41218, Tanzania
Department of Environmental Engineering and Management, Faculty of Natural Sciences, L.N. Gumilyov Eurasian National University, Satpayev Street 2, Astana, 010000, Kazakhstan
Department of Medical Genetics and Molecular Biology, Astana Medical University, Beibitshilik Street 49a, Astana, 010000, Kazakhstan
Department of Biomedicine, Karaganda Medical University, Gogolya Street, 40, Karaganda, 100000, Kazakhstan
Department of Morphology, Institute of Life Sciences, Karaganda Medical University, Alalykin Street 7, Karaganda, 100012, Kazakhstan
Faculty of Engineering. Department of Ecology and Geology, Yeesenov University, 32, Aktau, 130000, Kazakhstan

Department of Environmental Engineering and Management
Department of Environmental Engineering and Management
Department of Medical Genetics and Molecular Biology
Department of Biomedicine
Department of Morphology
Faculty of Engineering. Department of Ecology and Geology

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