Synthesis, and characterization of palladium(II) and platinum(II) complexes with α‑hydroxy[1-(2-ethoxyethyl) piperidin-4-yl]phosphonate and use of the palladium(II) complex as pre-catalyst in Suzuki-Miyaura cross-coupling reactions
Kystaubayeva N.U. Durap F. Zharkynbek T.Y. Yu V.К. Aydemir M. Meriç N. Zazybin A.G. Ten Y. Rafikova K.S. Binbay N.E. Çelik Ö.
15 December 2022Elsevier B.V.
Journal of Molecular Structure
2022#1270
Complexes [MCl2{(L1}2] (M = Pd, Pt) were obtained by the reaction of the α-Hydroxy[1-(2-ethoxyethyl)piperidin-4-yl]phosphonate as ligand with [MCl2(COD)] (M = Pd, Pt). The new compounds were characterized by NMR and IR spectroscopy, and microanalysis. In addition, representative solid-state structure of the ligand was determined using single crystal X-ray diffraction analysis. Furthermore, ab initio quantum calculations of the ligand and its complexes were also carried out using density functional theory to better understand their chemical behaviors. Finally, the palladium(II) complex of the ligand was tested as a potential catalyst in the Suzuki-Miyaura cross-coupling reactions.
DFT calculations , Pd(II) and Pt(II) complexes , Suzuki-Miyaura reaction , α-hydroxy[1-(2-ethoxyethyl)piperidin-4-yl]phosphonate
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Kazakh-British Technical University, Tole-bi str., 59, Almaty, 050010, Kazakhstan
Institute of Chemical Sciences, Walikhanov str., 106, Almaty, 050010, Kazakhstan
Department of Chemistry, Science Faculty, Dicle University, Diyarbakir, 21280, Turkey
Al-Farabi Kazakh National University, Al-Farabi ave. 71/23, Almaty, 050040, Kazakhstan
Department of Electronics, Vocational School, Dicle University, Diyarbakir, 21280, Turkey
Smart Lab, Dicle University, Diyarbakir, 21280, Turkey
Kazakh-British Technical University
Institute of Chemical Sciences
Department of Chemistry
Al-Farabi Kazakh National University
Department of Electronics
Smart Lab
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