Synthesis and Growth of Rare Earth Borates NaSrR(BO3)2 (R = Ho− Lu, Y, Sc)
Kuznetsov A.B. Kokh K.A. Sagatov N. Gavryushkin P.N. Molokeev M.S. Svetlichnyi V.A. Lapin I.N. Kononova N.G. Shevchenko V.S. Bolatov A. Uralbekov B. Goreiavcheva A.A. Kokh A.E.
3 May 2022American Chemical Society
Inorganic Chemistry
2022#61Issue 197497 - 7505 pp.
NaSrR(BO3)2 (R = Ho−Lu, Y, Sc) compounds were obtained for the first time. Their structures exhibit disordered positions of Sr2+ and Na+ atoms while RO6 polyhedra are connected through the BO3 groups. Large distances between R atoms and high transparency in the range of 250−900 nm make them promising for phosphor applications. A pathway to obtain single crystals was shown by growing NaSrY(BO3)2 and NaSrYb(BO3)2 by the top seeded solution growth method with Na2OB2O3-NaF flux.
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Sobolev Institute of Geology and Mineralogy SB RAS, Novosibirsk, 630090, Russian Federation
Novosibirsk State University, Novosibirsk, 630090, Russian Federation
Kemerovo State University, Kemerovo, 650000, Russian Federation
Kirensky Institute of Physics, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, 660036, Russian Federation
Tomsk State University, Tomsk, 634050, Russian Federation
Al-Farabi Kazakh National University, Center of Physical-Chemical Methods of Research and Analysis, Almaty, 050040, Kazakhstan
Sobolev Institute of Geology and Mineralogy SB RAS
Novosibirsk State University
Kemerovo State University
Kirensky Institute of Physics
Tomsk State University
Al-Farabi Kazakh National University
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