Catalytic performance of Ru(0) nanoparticles supported on K-OMS-2 in transfer hydrogenation reactions
Kizil F. Önal H.İ. Rafikova K. Koyuncu F. Satybaldi̇yeva N. Aronova A.A. Selenova B. Durap F. Aydemir M.
5 February 2026Elsevier B.V.
Applied Catalysis A: General
2026#711
Transfer hydrogenation-mediated reduction of ketones to yield secondary alcohols, which leads to the production of commercially important fine chemicals, is more favorable compared to conventional hydrogenation reactions. This research explores the effects of different Ru(0) nanoparticle loadings synthesized by treating a cryptomelane-type manganese oxide framework (K-OMS-2), which were characterized by advanced analytical methods including FT-IR, XRD, XPS, BET, SEM-EDX, and HR-TEM-EDX. The catalytic activity of Ru(0)@K-OMS-2 nanocatalyst was investigated in the transfer hydrogenation reaction of ketones. According to the catalytic results, Ru(0)@K-OMS-2 (3.0 %) catalyst containing 3 wt% Ru showed higher efficiency, high selectivity and high conversion (97 %) in transfer hydrogenation compared to other catalysts prepared in this study.
Alcohol , Catalysis , K-OMS-2 , Ketones , Nanoparticles , Ruthenium , Transfer Hydrogenation
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Dicle University, Science Faculty, Department of Chemistry, Diyarbakır, 21280, Turkey
Batman University, Energy Coordination Office, Batman, 72000, Turkey
Satbayev University, Department of Chemical and Biochemical Engineering, Almaty, Kazakhstan
Dicle University, Science and Technology Application and Research Center (DUBTAM), Diyarbakir, 21280, Turkey
Dicle University
Batman University
Satbayev University
Dicle University
10 лет помогаем публиковать статьи Международный издатель
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