Bitumen Extraction from Bituminous Sands by Ultrasonic Irradiation

Imanbayev Y. Ongarbayev Y. Abylaikhan A. Mussabayeva B. Muktaly D. Myltykbayeva Z.
October 2025 Multidisciplinary Digital Publishing Institute (MDPI)

ChemEngineering
2025 #9 Issue 5

This paper discusses the efficiency of ultrasonic-assisted bitumen extraction from bituminous sands of the Beke deposit (Mangistau region, Kazakhstan) using alkaline aqueous solutions. The process parameters, including ultrasonic frequency (22 kHz), power (up to 1500 W), solution pH (>12), and optimal NaOH concentration (1 wt.%) were optimized to achieve a maximum bitumen recovery of 98 wt.% within 8 min. The most effective sand-to-solution mass ratio was determined as 1:2, while the optimal process temperature was 75 °C. The application of ultrasound significantly enhances cavitation and reagent penetration, enabling efficient separation of bitumen with minimal chemical usage. Fourier-transform infrared (FTIR) spectroscopy and GC–MS analyses revealed the presence of aromatic hydrocarbons, paraffinic and naphthenic structures, as well as sulfur- and oxygen-containing functional groups (e.g., sulfoxides, carboxylic acids). These characteristics suggest moderate maturity and a high degree of aromaticity of the organic matter. Despite suitable thermal and compositional properties, the extracted bitumen exhibits a relatively low stiffness and softening point, indicating the need for additional upgrading (e.g., oxidation) prior to use in road construction. Although standard rheological tests (e.g., dynamic shear rhinometry) were not conducted in this study, the penetration and softening point values suggest a relatively soft binder, possibly unsuitable for high-temperature paving applications without modification. Future research will focus on rheological evaluation and oxidative upgrading to meet the ST RK 1373-2013 specification requirements.

alkaline solution , bituminous sands , irradiation intensity , natural bitumen , ultrasound irradiation

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Institute of Combustion Problems, Bogenbay Batyr St., 172, Almaty, 050012, Kazakhstan
Faculty of Chemistry and Chemical Technology, Al-Farabi Kazakh National University, al-Farabi Av., 7, Almaty, 050040, Kazakhstan
Pedagogical Institute, Astana International University, Kabanbai Batyr Av., 8, Astana, 020000, Kazakhstan

Institute of Combustion Problems
Faculty of Chemistry and Chemical Technology
Pedagogical Institute

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