DART Mass Spectrometry in the Analysis of Organometallic Complexes


Goryainov S.V. Esparza C. Kulikova L.N. Borisova A.R. Kumandin P.A. Antonova A.S. Rystsova E.O. Oshakbaev M.T. Omarova G.T. Polovkov N.Y.
December 2021Pleiades journals

Journal of Analytical Chemistry
2021#76Issue 131520 - 1524 pp.

Abstract: We recorded and interpreted DART mass spectra of Hoveyda–Grubbs catalysts with N→Ru and S→Ru coordination bonds. The set of ions formed under DART ionization conditions is similar to those obtained using matrix-assisted laser desorption/ionization mass spectrometry. The optimal conditions (ionization gas, gas flow temperature) for recording DART mass spectra of the studied compounds were determined.

DART , Grubbs catalysts , mass spectrometry , organometallic complexes

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Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, 119991, Russian Federation
RUDN University, Moscow, 117198, Russian Federation
Berkutov Institute of Chemical Sciences, Almaty, 050010, Kazakhstan

Topchiev Institute of Petrochemical Synthesis
RUDN University
Berkutov Institute of Chemical Sciences

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