Investigation of the Phase Composition, Structural, Mechanical, and Dielectric Properties of (1 − x)∙ZrO2-x∙CeO2 Ceramics Synthesized by the Solid-State Method


Giniyatova S.G. Shakirzyanov R.I. Garanin Y.A. Sailaukhanov N.A. Kozlovskiy A.L. Volodina N.O. Shlimas D.I. Borgekov D.B.
March 2024Multidisciplinary Digital Publishing Institute (MDPI)

Applied Sciences (Switzerland)
2024#14Issue 6

Ceramics based on zirconium dioxide are very important compounds for dental, implant, and structural material applications. Despite the fact that tetragonally stabilized YSZ has been well studied, the search for new compositions of zirconia-based ceramics is still in progress. The ZrO2-CeO2 system is one of the alternatives for YSZ materials, but there is conflicting experimental data on its phase composition and mechanical properties depending on the ratio of components. In this study, we investigated the phase composition, and microstructural, mechanical, and physical properties of (1 − x)∙ZrO2-x∙CeO2 (step of x = 0.05) ceramics obtained by the solid-state sintering process from micron-sized powders. For the characterization of samples, XRD, Raman spectroscopy, SEM, the Vickers Microhardness Test, and dielectric spectroscopy were implemented. The results showed that by varying the CeO2 concentration, it is possible to synthesize stable tetragonal ZrO2 at room temperature with a high microhardness HV0.05 value of ~1500, low porosity (~2.5%), and a high dielectric constant of 36. The pronounced combined effect of tetragonal phase formation, densification, and grain size reduction on the mechanical and dielectric properties of the experimental samples was investigated. Refined experimental data make it possible to synthesize high-quality zirconia–ceria ceramics for use as refractories, dispersed nuclear fuel, or solid oxide fuel cells.

ceria , microhardness , microstructure , permittivity , tetragonal zirconia

Text of the article Перейти на текст статьи

Engineering Profile Laboratory, L.N. Gumilyov Eurasian National University, Satpayev St., Astana, 010008, Kazakhstan
Laboratory of Solid State Physics, The Institute of Nuclear Physics, Almaty, 050032, Kazakhstan

Engineering Profile Laboratory
Laboratory of Solid State Physics

10 лет помогаем публиковать статьи Международный издатель

Книга Публикация научной статьи Волощук 2026 Book Publication of a scientific article 2026