Application of pulse current for dissolution of heat-resistant GS32-VI alloy
Chernyshova О.V. Yelemessov Т.B. Drobot D.V.
2021MIREA - Russian Technological University
Tonkie Khimicheskie Tekhnologii
2021#16Issue 5438 - 447 pp.
Objectives. To identify the regularities of electrochemical processing of the heat-resistant GS32-VI alloy in a sulfuric acid electrolyte with a concentration of 100 g/dm3 under the action of a pulsed current in a pulsed mode. Methods. Using the electrochemical technological complex EHK-1012 (developed by IP Tetran) and a non-compensatory method of measuring potential, polarization and depolarization curves with a change in pulse duration and a pause between them were recorded. The current pulses had an amplitude ranging from 0 to 3.5 A (when recording the polarization and depolarization curves), pulse durations ranging from 200 to 1200 ms, and a pause (delay) between pulses ranging from 50 to 500 ms. There were no reverse current pulses. Results. The parameters of the current program that provide the maximum values of the alloy dissolution rate and current output were determined: with a current pulse amplitude of 2 A, a current pulse duration of 500 ms, and a pause duration between pulses of 250 ms, the maximum dissolution rate of the alloy is 0.048 g/h·cm2, while the current output for nickel is 61.6% with an anode area of 10 cm2. The basic technological scheme for processing the heat-resistant GS32-VI alloy, which includes anodic alloy dissolution in a pulsed mode, is proposed. Conclusions. Electrochemical dissolution of GS32-VI alloy under pulsed current action results in an optimal dissolution rate ratio of the alloy components, ensuring the production of a cathode precipitate with a total nickel and cobalt content of 97.5%.
Amplitude of pulse current , Duration of pulse current , GS32-VI alloy , Pause between pulse current , Polarization and depolarization curves , Pulse current , Sulfuric acid
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MIREA – Russian Technological University (M.V. Lomonosov Institute of Fine Chemical Technologies), Moscow, 119571, Russian Federation
Institute of High Technologies, Almaty, 050012, Kazakhstan
MIREA – Russian Technological University (M.V. Lomonosov Institute of Fine Chemical Technologies)
Institute of High Technologies
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