Recent trends in dehydroxylative trifluoro-methylation, -methoxylation, -methylthiolation, and -methylselenylation of alcohols
Cao Y. Ahmadi R. Poor Heravi M.R. Issakhov A. Ebadi A.G. Vessally E.
13 December 2021Royal Society of Chemistry
RSC Advances
2021#11Issue 6239593 - 39606 pp.
Owing to the prevalence of hydroxyl groups on molecules, much attention has been paid to the synthesis of functionalized organic compounds by dehydroxylative functionalization of parent alcohols. In this context, dehydroxylative trifluoromethylation, trifluoromethoxylation, trifluoromethylthiolation, and trifluoromethylselenylation of readily available alcohols have recently emerged as intriguing protocols for the single-step construction of diverse structures bearing C-CF3, C-OCF3, C-SCF3, and C-SeCF3bonds, respectively. This Mini-Review aims to summarize the major progress and advances in this appealing research area with special emphasis on the mechanistic features of the reaction pathways.
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School of Mechatronic Engineering, Xian Technological University, Xian, 710021, China
Department of Chemistry, College of Basic Sciences, Yadegar-e-Imam Khomeini (RAH) Shahre Rey Branch, Islamic Azad University, Tehran, Iran
Department of Chemistry, Payame Noor University, P.O. Box 19395-3697, Tehran, Iran
Department of Mathematical and Computer Modelling, al-Farabi Kazakh National University, Almaty, 050040, Kazakhstan
Department of Mathematics and Cybernetics, Kazakh British Technical University, Almaty, 050000, Kazakhstan
Department of Agriculture, Jouybar Branch, Islamic Azad University, Jouybar, Iran
School of Mechatronic Engineering
Department of Chemistry
Department of Chemistry
Department of Mathematical and Computer Modelling
Department of Mathematics and Cybernetics
Department of Agriculture
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