Alkylative/arylative carboxylation of unsaturated hydrocarbons utilizing CO2 as C1 synthon: An update
Cao Y. A. Dhahad H. Hussen H.M. E. Anqi A. Farouk N. Issakhov A. Heravi M.R.P.
October 2021Elsevier Ltd
Journal of CO2 Utilization
2021#52
The difunctionalization of unsaturated hydrocarbons, the incorporation of two functional groups onto an unsaturated carbon-carbon bonds, is one of the most active and popular topics in modern organic chemistry due to its significance in the rapid and highly atom economical synthesis of complex molecules from simple starting materials within a single click. Among various difunctionalization reactions, difunctionalizing carboxylations utilizing CO2 as a renewable and environmental friendly C1 feedstock has attracted more and more attention in recent years. In this regard, several interesting strategies have been developed in the last two decades for the preparation of branched carboxylic acids and their derivatives through the alkylative/arylative carboxylation of the corresponding unsaturated hydrocarbons using CO2 as a carboxyl source. Thus, it is an appropriate time to summarize those advances. The purpose of this Mini-Review is to focus on the most important advances and developments on the attractive research field with particular emphasis on the mechanistic features of the reaction pathways. Notably, we have organized this review based on the type of bond where the CO2 insertion occurs.
Carbocarboxylation , Carbon dioxide , Carboxylic acids , Difunctionalization , Unsaturated hydrocarbons
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School of Mechatronic Engineering, Xian Technological University, Xian, 710021, China
Mechanical Engineering Department, University of Technology, Baghdad, Iraq
Department of Mechanical Engineering, College of Engineering, King Khalid University, Abha, 61421, Saudi Arabia
Mechanical Engineering Department, College of Engineering, Prince Sattam Bin Abdulaziz University, Alkharj, 16273, Saudi Arabia
Mechanical Engineering Department, Faculty of Engineering, Red Sea University Port Sudan, Sudan
Department of Mathematical and Computer Modelling, al-Farabi Kazakh National University, Almaty, 050040, Kazakhstan
Department of Mathematics and Cybernetics, Kazakh British Technical University, Almaty, 050000, Kazakhstan
Department of Chemistry, Payame Noor University, Tehran, Iran
School of Mechatronic Engineering
Mechanical Engineering Department
Department of Mechanical Engineering
Mechanical Engineering Department
Mechanical Engineering Department
Department of Mathematical and Computer Modelling
Department of Mathematics and Cybernetics
Department of Chemistry
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