Optical and photovoltaic properties of organic solar cells versus bulk-heterojunction morphology


Asanov N. Schopp N. Valagiannopoulos C. Brus V.
15 May 2024American Physical Society

Physical Review B
2024#109Issue 20

It has long been argued that the performance of organic bulk-heterojunction solar cells critically depends on the morphology of the active layer, a mixture of donor and acceptor materials in which the charge generation from sunlight occurs. In this work, optical homogenization principles are utilized to model the structure of the common active layer PM6:Y6. By systematically modifying the size and shape of Y6 acceptor inclusions within the morphology, we explore how these changes influence the refractive index and extinction coefficient of the resulting effective medium. A synergy of transfer matrix optical simulations with the Hecht equation is used to evaluate the effect of the inclusions features on the external quantum efficiency spectrum. The reported findings can be particularly helpful in the fabrication of similar classes of organic solar cells by indicating which aspects of active layer mixture may undermine the expected performance of the photovoltaic cells.



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Department of Physics, Nazarbayev University, Astana, KZ-01000, Kazakhstan
First Solar Inc., Perrysburg, 43551, OH, United States
School of Electrical and Computer Engineering, National Technical University of Athens, Athens, GR-15780, Greece
First Solar Inc., Perrysburg, 43551, OH, United States

Department of Physics
First Solar Inc.
School of Electrical and Computer Engineering
First Solar Inc.

10 лет помогаем публиковать статьи Международный издатель

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