Catalyst- and Solvent-Free Hydrophosphorylation of Aldimines with Secondary Phosphine Chalcogenides: Synthesis of Tertiary α-Aminophosphine Oxides, Sulfides and Selenides
Arbuzova S.N. Verkhoturova S.I. Zinchenko S.V. Kolyvanov N.A. Chernysheva N.A. Bishimbaeva G.K. Trofimov B.A.
6 December 2022John Wiley and Sons Inc
ChemistrySelect
2022#7Issue 45
Secondary phosphine chalcogenides mildly (no catalysts and solvents, 20–65 °C, 0.25–65.5 h) react with aldimines to deliver the hitherto unknown α-aminophosphine oxides, sulfides and selenides in good to excellent yields.
green chemistry , hydrophosphorylation , Schiff bases , secondary phosphine chalcogenides , α-aminophosphine chalcogenides
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A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, 1 Favorsky Str., Irkutsk, 664033, Russian Federation
D. V. Sokolskiy Institute of Fuel, Catalysis and Electrochemistry, 142 ul. Kunaeva, Almaty, 050010, Kazakhstan
A. E. Favorsky Irkutsk Institute of Chemistry
D. V. Sokolskiy Institute of Fuel
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