Hydrogen distribution in primary coke oven tar and its fractions
Aitbekova D.E. Makenov D.K. Andreikov E.I. Tsaur A.G. Ma F.Y. Baikenova G.G. Tusipkhan A. Muratbekova A.A. Baikenov M.I.
2021E.A.Buketov Karaganda State University Publish House
Bulletin of the Karaganda University Chemistry Series
2021#101Issue 182 - 90 pp.
The aim of this work is to determine the hydrogen distribution in primary coke oven tar and its fractions. The hydrogen distribution in the primary coke oven tar of «ShubarkolKomir» JSC, its distillate fractions and distillation residue have been determined by the methods of elemental analysis, IR and PMR spectroscopy. The atomic ratio of C: H in the primary coke oven tar is 0.79. All fractions of the tar contain a large amount of alkyl-substituted aromatic compounds, phenols and other substances with alkyl groups. The initial tar characterized by a high content of hydrogen in the α- and β-positions to the aromatic ring, 29 % and 34 % respectively, which indicates a large number of alkyl substituents in the aromatic rings and near double bonds. The total amount of aliphatic and aromatic hydrogen in the tar is 79 % and 21 % respectively. Olefinic hydrogen is presented in the initial tar in an amount of 8 %. It is possible to make a choice of techniques for further processing (hydrogenation, coking, thermal cracking) to obtain products with high added value on the basis of determination of the elemental composition, quantitative distribution of hydrogen in the primary coke oven tar and its fractions by the using of above mentioned physical and chemical methods.
Elemental analysis , Hydrogen distribution , IR spectroscopy , PMR spectroscopy , Primary coke oven tar , Tar fractions
Text of the article Перейти на текст статьи
Karagandy University of the name of academician E.A., Buketov, Kazakhstan
Postovsky Institute of Organic Synthesis UB RAS, Ekaterinburg, Russian Federation
Eastern Research Institute of Coal Chemistry, Ekaterinburg, Russian Federation
Xinjiang University, Xinjiang Uyghur Autonomous Region, China
Karaganda Economic University of Kazpotrebsoyuz, Karaganda, Kazakhstan
South Ural State University, Chelyabinsk, Russian Federation
Karagandy University of the name of academician E.A.
Postovsky Institute of Organic Synthesis UB RAS
Eastern Research Institute of Coal Chemistry
Xinjiang University
Karaganda Economic University of Kazpotrebsoyuz
South Ural State University
10 лет помогаем публиковать статьи Международный издатель
Книга Публикация научной статьи Волощук 2026 Book Publication of a scientific article 2026