Complex Compounds Based on Pinostrobin Oxime
Adekenov S.M. Baysarov G.M. Zhabayeva A.N. Suntsova L.P. Dushkin A.V.
2021Altai State University
Khimiya Rastitelnogo Syrya
2021Issue 1219 - 226 pp.
The article studied the structural features of solid dispersions of pinostrobin oxime with arabinogalactan, disodium salt of glycyrrhizic acid, polyvinylpyrrolidone and basic magnesium carbonate obtained by mechanochemical treatment. The obtained complexes of pinostrobin oxime with arabinogalactan, disodium salt of glycyrrhizic acid, polyvinylpyrrolidone, and basic mag-nesium carbonate have increased water solubility in comparison with the initial pinostrobin oxime. The thermal effects of pi-nostrobin oxime and its complex compounds have been studied by differential scanning calorimetry. At the same time, on the DSC-curve, the melting peak of solid dispersions of pinostrobin oxime with disodium salt of glycyrrhizated acid and pinostrobin oxime with arabinogalactan is not displayed, which is associated with the intermolecular interaction of the components of the complex, where the molecule of pinostrobin oxime forms a bond with a complexformation agent during mechanochemical treat-ment. The complex of pinostrobin oxime with magnesium carbonate is not formed, as evidenced by the thermal curve, where the melting of the sample begins at 182 °C, and complete destruction occurs at a temperature of 782 °C, which is similar to the melting peak of the initial pinostrobin oxime. The results of studying intermolecular bonds in complexes of pinostrobin oxime by the method of NMR-relaxation indicate that the times of spin-lattice and spin-spin relaxation are very sensitive to intermolecular interaction and to the diffusion mobility of molecules.
arabinogalactan , basic magnesium carbonate , complex compounds , differential scanning calorimetry , disodium salt of glycyrrhizic acid , Pinostrobin , pinostrobin oxime , polyvinylpyrrolidone
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JSC International Scientific and Production Holding Phytochemistry, ul. M. Gazalieva, 4, Karaganda, 100009, Kazakhstan
Institute of Solid State Chemistry and Mechanochemistry, SBRAS, ul. Kutateladze, 18, Novosibirsk, 630128, Russian Federation
JSC International Scientific and Production Holding Phytochemistry
Institute of Solid State Chemistry and Mechanochemistry
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