Strategic Synthesis of 2D and 3D Conducting Polymers and Derived Nanocomposites
Abutalip M. Zhigerbayeva G. Kanzhigitova D. Askar P. Yeszhan Y. Pham T.T. Adilov S. Luque R. Nuraje N.
2 February 2023John Wiley and Sons Inc
Advanced Materials
2023#35Issue 5
In recent decades, there has been a great deal of interest in conducting polymers due to their broad applications. At the same time, various synthetic techniques have been developed to produce various nanostructures of the conducting polymers with their fascinating properties. However, the techniques for the manufacture of 2D nanosheets are either complex or expensive. No comprehensive approach for constructing 2D and 3D materials or their composites has been documented. Herein, a simple and scalable synthetic protocol is reported for the design of 2D, 3D, and related conducting polymer nanocomposites by interface manipulation in a bicontinuous microemulsion system. In this method, diverse bicontinuous thin layers of oil and water are employed to produce 2D nanosheets of conducting polymers. For the fabrication of 3D polypyrrole (PPY) and their composites, specially designed linkers of the monomers are applied to lock the 3D networks of the conducting polymers and their composites. The technique can be extended to the fabrication of most conducting polymer composites, being cost-effective and easily scalable. The optimum electrical conductivity obtained for 2D PPY nanosheets is 219 S cm−1, the highest literature value reported to date to the best of knowledge.
conducting polymers , electronic properties , polyaniline
Text of the article Перейти на текст статьи
Department of Chemical & Materials Engineering, School of Engineering & Digital Science, Nazarbayev University, Astana, 010000, Kazakhstan
Lab of Renewable Energy Systems & Materials Science, National Laboratory Astana, Nazarbayev University, Astana, 010000, Kazakhstan
Department of Chemistry and Chemical Technology, Al-Farabi Kazakh National University, Almaty, 050040, Kazakhstan
Department of Biology, School of Sciences and Humanities, Nazarbayev University, Astana, 010000, Kazakhstan
Department of Chemistry, School of Sciences and Humanities, Nazarbayev University, Astana, 010000, Kazakhstan
Departamento de Química Orgánica, Universidad de Córdoba, Campus de Rabanales, Edificio Marie Curie (C-3), Ctra Nnal IV-A, Km 396, Cordoba, E14014, Spain
Peoples Friendship University of Russia (RUDN University), 6 Miklukho Maklaya str., Moscow, 117198, Russian Federation
Department of Chemical & Materials Engineering
Lab of Renewable Energy Systems & Materials Science
Department of Chemistry and Chemical Technology
Department of Biology
Department of Chemistry
Departamento de Química Orgánica
Peoples Friendship University of Russia (RUDN University)
10 лет помогаем публиковать статьи Международный издатель
Книга Публикация научной статьи Волощук 2026 Book Publication of a scientific article 2026